Schema-less/flexible + ACID database?

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http://serverfault.com – I am looking at rewriting a VB based on-premise (locally installed) application (invoicing+inventory) as a web based Clojure application for small enterprise customers. I am intending this to be offered as a SaaS application for customers in similar trade. I was looking at database options: My choice was an RDBMS: Postgresql/ MySQL. I might scale up to 400 users in the first year, with typically a 20-40 page views/ per day per user - mostly for transactions not static views. Each view will involve fetch data and update data. ACID compliance is necessary(or so I think). So the transaction volu (HowTos)