No Audio Output with X11

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http://unix.stackexchange.com – I have a queer issue with my Arch-Linux System. I am unable to get any Sound Output when playing audio, AFTER starting X Server. The issue is not with Volume Controls or Sound Card Drivers because, if I start any kind of Audio playback BEFORE starting X Server, I have absolutely no issues. The Audio keeps playing even after X Server starts. But if I pause / stop the audio, on restarting playback, I get no audio output. Even terminating X Server does not resolve this issue. Rebooting the system though, helps. I am not sure what files I should be checking for this. Could any please guide m (HowTos)