Network Administration Reading

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http://forums.fedoraforum.org – I am having to train someone in to do Network Administration for a private school. Our environment is a mix of Mac OS X, Windows and Linux systems. I am thinking training him to use Linux will give him the skills necessary for working with the other two platforms. What reading can I give him, and what can I be doing to train him? His experience in the past has involved some programming, but he is so rusty with it just showing him a basic C or C++ "Hello, World!" seems to be daunting. Any recommendations? (HowTos)