Improve sound quality

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http://forums.fedoraforum.org – I have realtek ALC861 and running fedora 17 LXDE 32bit. Are there some tips or tricks to improve sound quality? Because comparing the same audio source, in windows with realtek manager, the sound was better. As i see fedora LXDE is using pulseaudio. Should i set up pulseaudio as audio output in VLC player? thx. (HowTos)