Headphone settings

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http://forums.fedoraforum.org – I'm running F19 with Xfce, fully updated. If I plug my headphones into a jack on the front panel of my desktop, I hear sound from them, but the speakers don't mute. And, as the whole object of the exercise is to be able to listen to music or play noisy FPS games without bothering other people, this isn't much help. Does anybody know how to tell Linux how I want my sounds handled? (HowTos)