Dynamically Selecting What Goes Through OpenVPN?

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http://www.linuxquestions.org – Is there a relatively easy way to selecting what goes through a VPN and what doesn't? Some times I would like my browser traffic to go through a VPN to avoid censorship, but other times I need the security of a 'direct' connection. Also, some applications like Deluge should never go through my VPN and others should only go through a VPN? Thanks (HowTos)