Avoid problems when scaling a large Word 2010 Documentation

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http://superuser.com – I don't have much experience with word-documents, so I'm asking for some helpful friendly suggestions what to pay attention to when making a large word document with lots of hyperlinks and embedded files. Background: I want to use Word 2010 to document a web-application and related database-code. (Goal: see that code actually implements business rules). My idea is to divide the document into two sections: Use-Cases, Code. Others would navigate through the document via hyperlinks. Consider the following workflow: Read the use case to create a new user. Here it says the user has to go to some (HowTos)